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The intermolecular forces present in CO include which of the following I. dipole-dipole II. ion-dipole III. dispersion IV. hydrogen bonding


A) I, II, III, and IV
B) I and III
C) I, III, and IV
D) I and II
E) II and IV

F) C) and D)
G) A) and B)

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How much energy (heat) is required to convert 52.0 g of ice at -10.0 \circ C to steam at 100 \circ C specific heat of ice: 2.09 J/gCΔHfus=6.02 kJ/mol \quad 2.09 \mathrm{~J} / \mathrm{g} \cdot{ }^{\circ} \mathrm{C} \quad \Delta \mathrm{H}_{\mathrm{fus}}=6.02 \mathrm{~kJ} / \mathrm{mol} specific heat of water: 4.18 J/gCΔHvap=40.7 kJ/mo 4.18 \mathrm{~J} / \mathrm{g}{ \cdot}^{\circ} \mathrm{C} \quad \Delta \mathrm{H}_{\mathrm{vap}}=40.7 \mathrm{~kJ} / \mathrm{mo} . specific heat of steam: 1.84 J/gC 1.84 \mathrm{~J} / \mathrm{g} \cdot{ }^{\circ} \mathrm{C}


A) 40.2 kJ
B) 157.8 kJ
C) 1,086 kJ
D) 2,570 kJ
E) 22,957 kJ

F) A) and B)
G) C) and E)

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The specific heat of liquid ethanol, C2H5OH(l) , is 2.46 J/g· \circ C and the heat of vaporization is 39.3 kJ/mol. The boiling point of ethanol is 78.3 \circ C. What amount of enthalpy is required to heat 50.0 g of liquid ethanol from 23.0 \circ C to ethanol vapor at 78.3 \circ C


A) 42.7 kJ
B) 49.5 kJ
C) 179 kJ
D) 1970kJ
E) 6840 kJ

F) C) and E)
G) A) and E)

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Based on the phase diagram shown below, the solid phase is more dense than the liquid phase. Based on the phase diagram shown below, the solid phase is more dense than the liquid phase.

A) True
B) False

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The normal boiling point of methanol (CH3OH) is 64.6 \circ C. Given that the vapor pressure of methanol is 75.0 torr at 15.2 \circ C, calculate the molar enthalpy of vaporization of methanol.


A) 0.383 kJ/mol
B) 3.00 kJ/mol
C) 27.5 kJ/mol
D) 38.0 kJ/mol
E) 74.7 kJ/mol

F) C) and E)
G) A) and B)

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The density of ice is less than the density of liquid water due to the formation of hydrogen bonds.

A) True
B) False

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Which of the following properties indicates the presence of strong intermolecular forces in a liquid


A) a low heat of vaporization
B) a low critical temperature
C) a low vapor pressure
D) a low boiling point
E) None of the above.

F) D) and E)
G) All of the above

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SrF2 crystallizes such that the Sr2+ ions are in a face-centered cubic arrangement and the F- ions are in the holes of the lattice (fluorite structure) . How many F- ions are present in one unit cell of this crystal


A) 1
B) 2
C) 4
D) 6
E) 8

F) A) and E)
G) C) and D)

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A phase change from the gas phase directly to the solid phase is called:


A) Sublimation
B) Condensation
C) Freezing
D) Melting
E) Deposition

F) B) and C)
G) A) and E)

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Which one of the following substances crystallizes as a molecular solid


A) KI
B) SiO2
C) Sn
D) CH3OH
E) Al2(SO4) 3

F) A) and B)
G) B) and E)

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Methane has a heat of fusion of 0.84 kJ/mol and a heat of vaporization of 9.2 kJ/mol. Estimate the value for the heat of sublimation.


A) 12.0 kJ/mol
B) 11.0 kJ/mol
C) 10.0 kJ/mol
D) 9.00 kJ/mol
E) 8.00 kJ/mol

F) D) and E)
G) B) and E)

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What mass of water would need to evaporate from your skin in order to dissipate 1.7 * 105 J of heat from your body H2O(l) \rarr H2O(g) Δ\Delta Hvap = 40.7 kJ/mol


A) 58.4 g
B) 75.2 g
C) 418 g
D) 7.52 * 104 g
E) 6.92 * 106 g

F) D) and E)
G) C) and D)

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Potassium crystallizes in a body-centered cubic lattice. How many atoms are there per unit cell


A) 1
B) 2
C) 4
D) 6
E) 8

F) C) and D)
G) A) and B)

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A liquid boils when its


A) vapor pressure is exactly 1 atmosphere.
B) vapor pressure is equal to, or greater than, the external pressure pushing on it.
C) temperature is equal to 273 K (standard temperature) .
D) temperature is greater than room temperature.

E) C) and D)
F) A) and D)

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Which one of the following substances should exhibit hydrogen bonding in the liquid state


A) PH3
B) He
C) H2S
D) CH4
E) CH3OH

F) B) and E)
G) D) and E)

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Indicate all the types of intermolecular forces of attraction in C2H6(g) .


A) Dispersion and Dipole-dipole
B) Dipole-dipole and Ionic
C) Ion-dipole and Hydrogen bonding
D) Hydrogen bonding and Dispersion
E) Dispersion

F) B) and D)
G) A) and D)

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Arrange the following substances in order of increasing boiling point: CH3OH, He, CH3Cl, and N2


A) CH3OH < He < CH3Cl < N2
B) He < N2 < CH3OH < CH3Cl
C) N2 < He < CH3OH < CH3Cl
D) He < N2 < CH3Cl < CH3OH
E) CH3Cl < He < N2 < CH3OH

F) B) and D)
G) C) and D)

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Osmium tetroxide, OsO4, is a soft crystal that melts at 40 \circ C. The liquid does not conduct electricity. What kind of crystal is this


A) Ionic Crystal
B) Covalent Crystal
C) Metallic Crystal
D) Molecular Crystal
E) Amorphous (Not a regular crystal)

F) A) and B)
G) B) and E)

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Which of the following substances is expected to have the highest molar heat of vaporization ( Δ\Delta Hvap)


A) Ar
B) C6H6
C) He
D) NH3
E) H2O

F) All of the above
G) C) and D)

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Which one of the following substances crystallizes as a covalent crystal


A) CaO
B) SiO2
C) CO2
D) Pb
E) KMnO4

F) D) and E)
G) All of the above

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