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Write the formula for pentaamminechlorocobalt(III) chloride.


A) [Co(NH3) 5Cl]Cl
B) [Co(NH3) 5Cl]Cl2
C) [Co(NH3) 5Cl]Cl3
D) [Co(NH3) 5Cl]Cl4
E) none of the above

F) A) and E)
G) A) and D)

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In the compound K[Co(C2O4) 2(H2O) 2] (where C2O42- = oxalate) the oxidation number and coordination number of cobalt are, respectively:


A) -1 and 4.
B) -1 and 6.
C) 3 and 4.
D) 3 and 6.
E) 1 and 6.

F) B) and C)
G) A) and B)

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The ground state electron configuration of a transition element atom cannot have more than one incomplete subshell.

A) True
B) False

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In the compound [Ni(en) 2(H2O) 2]SO4 (where en = ethylenediamine) the oxidation number and coordination number of nickel are, respectively:


A) 2 and 6.
B) 4 and 6.
C) 6 and 6.
D) 2 and 4.
E) 4 and 4.

F) None of the above
G) B) and D)

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The maximum oxidation state of an element in the first transition series never exceeds its group number.

A) True
B) False

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What is the difference between a coordination compound and a complex ion?

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A coordination compound genera...

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Mercury(II) compounds are assimilated into the food chain because


A) they are ionic substances that are concentrated in cell tissue.
B) they complex with compounds in the blood which carries them to the muscle tissue of organisms.
C) they are incorporated into bone structure.
D) they are very soluble in water and easily ingested.
E) they are nonpolar substances that are concentrated in fatty tissues as they move up the food chain.

F) B) and D)
G) A) and E)

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Which of the following coordination numbers applies to octahedral complexes?


A) 4
B) 5
C) 6
D) 8
E) none of the above

F) B) and E)
G) C) and D)

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Which of the following transition elements can achieve the largest oxidation number?


A) chromium, Cr, Group 6B(6)
B) manganese, Mn, Group 7B(7)
C) iron, Fe, Group 8B(8)
D) cobalt, Co, Group 8B(9)
E) zinc, Zn, Group 2B(12)

F) All of the above
G) C) and D)

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Iron(III) forms an octahedral complex with the ligand CN-. How many unpaired electrons are in the d orbitals of iron?


A) 1
B) 3
C) 5
D) 7
E) none of the above

F) A) and B)
G) None of the above

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In complexes of transition metals, the maximum coordination number of the metal is equal to its number of d electrons.

A) True
B) False

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a. How can the formation of a complex ion be described in terms of a theory of acids and bases? b. What is the essential requirement for a molecule or ion to act as a ligand?

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a. According to Lewis, in an acid-base r...

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